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Green Catalytic Hydrogenation of Phthalate Plasticizers（增塑剂绿色催化技术）


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Green Catalytic Hydrogenation of Phthalate Plasticizers（增塑剂绿色催化技术）
  • 书号：9787030724748
    作者：刘仲毅
  • 外文书名：
  • 装帧：圆脊精装
    开本：B5
  • 页数：291
    字数：400000
    语种：en
  • 出版社：科学出版社
    出版时间：2022-06-01
  • 所属分类：
  • 定价： ￥160.00元
    售价： ￥126.40元
  • 图书介质:
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  • 购买数量： 件  可供
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本书在国内外文献调研和实验室研究基础上，从物质结构和分子水平上阐述邻苯类增塑剂分子结构改性的微观机制，阐明苯环改性和酯基调控的多相催化机理以及产物分离、产品应用的科学依据，以及国内外相关法律法规，为增塑剂行业实现转型发展、绿色发展提供有益借鉴。
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目录

  • Contents
    1　Introduction　1
    1.1　Background　1
    1.2　Fundamentals of Plasticizers　6
    1.2.1　Symbols and Abbreviations　6
    1.2.2　Major Functions of Plasticizers　6
    1.2.3　Major Performance-Determining Factors for Plasticizers　10
    1.2.4　Mechanism for Plasticity Increase by Plasticizers　11
    1.2.5　Property Requirements for Plasticizers　13
    1.2.6　Inspection Standards for Plasticizers　18
    1.2.7　Types of Plasticizers　18
    1.3　Cyclohexane-1, 2-Dicarboxylate Plasticizers　22
    1.4　Environmentally Friendly Plasticizers　25
    1.5　Developmental Direction of Plasticizer Industry in China　26
    1.6　Main Contents of This Book　27
    References　27
    2　Foreign and Domestic Plasticizer Laws　33
    2.1　Foreign Plasticizer Laws, Evolution　33
    2.2　Domestic Plasticizer Laws and Evolution　33
    2.3　Interpretations of Foreign and Domestic Plasticizer Laws　37
    2.3.1　EU Bans　37
    2.3.2　EU’s REACH Policy [1,2]　39
    2.3.3　The EU’s RoHS [1,3]　40
    2.3.4　USA’s CPSIA　42
    2.3.5　Related Phthalate Laws in Other Countries　44
    2.3.6　Domestic Laws [4–6]　44
    2.4　Comparison and Trend of Plasticizer Laws for Food Contact Applications　47
    2.4.1　Current Status　47
    2.4.2　Chinese Laws and Regulations　47
    2.4.3　EU’s Laws and Regulations　47
    2.4.4　USA’s Laws and Regulations　48
    2.5　Conclusion　48
    References　49
    3　Current Status of Plasticizer Research　51
    3.1　Foreign Research Status　51
    3.1.1　Phthalate Hydrogenation Technology　51
    3.1.2　Research on Toxicity of Phthalate Compounds　55
    3.2　Domestic Research Status　55
    3.2.1　Synthesis of DIBCH(1999)[9]　55
    3.2.2　Synthesis of HHPA(2000)[10]　57
    3.3　Di(2-Propylheptyl) Phthalate (2006) [13]　59
    3.3.1　Physical Properties　59
    3.3.2　Performance　60
    3.4　Cyclohexane Dicarboxylate Plasticizers (2010)[14]　64
    3.4.1　Preparation of Cyclohexane Dicarboxylate Plasticizers　65
    3.4.2　Properties and Assessment of Cyclohexane Dicarboxylate Plasticizers　66
    3.4.3　Application Examples of Formulation　71
    3.4.4　Conclusion　72
    3.5　Development Status of Plasticizers (2010, 2011) [18,19]　73
    3.5.1　Status of Plasticizers in Foreign Countries　73
    3.5.2　Status of Plasticizers in China　73
    3.5.3　New Environmentally Friendly Plasticizers　75
    3.5.4　Sustainable Development of Plasticizers in China　75
    3.6　Diisononyl Cyclohexane-1,2-Dicarboxylate(2010,2014)[20,21]　76
    3.6.1　Physical Properties　77
    3.6.2　Production Routes of DINCH　77
    3.6.3　Applications of DINCH　79
    3.7　Environmentally Friendly Plasticizers　81
    3.7.1　Di(2-Ethylhexyl) Cyclohexane-1,2-Dicarboxylate Plasticizer(2011)[22]　81
    3.7.2　Research and Application Progress of Catalytic Synthesis of Environmentally Friendly Plasticizers(2012)[15]　83
    3.7.3　Innovations and Applications of Green Plasticizers[97]　91
    3.7.4　Technological Innovation and Market Dynamics of Green Plasticizers(2017)[98]　93
    3.8　Hydrogenation of Dioctyl Phthalate (2012)[34]　94
    3.9　Liquid-Phase Catalytic DOP Hydrogenation and Kinetics(2012)[50]　94
    3.10　Synthesis and Application of Environmentally Friendly DEHCH Plasticizer(2013)[38,113,114]　97
    3.11　Synthesis and Application of Environmentally Friendly DEHCH Plasticizer(2014–2015)　100
    3.11.1　Preparation of DOP Hydrogenation Catalyst(2014)[120]　100
    3.11.2　DEHP Hydrogenation Product Analysis Using GC-MC (2015)[42]　100
    3.12　Synthesis of DEHCH via Direct Esterification (2015)[121]　103
    3.13　Cable Industry’s Response to EU’s Newest Environmental Laws　108
    3.14　Applications of Environmentally Friendly Plasticizers in Disposable Gloves(2016)[127]　108
    3.15　Development and Application of Environmentally Friendly Polyester Plasticizers (2016)[128]　109
    3.16　How to Accurately Assess and Use Benzoate-Based Plasticizers?(2016)[129]　110
    3.17　Production Study of Environmentally Friendly DEHCH Plasticizer(2016)[130]　113
    3.18　Co-existing Opportunities and Challenges for DOP Market(2017)[115]　115
    3.19　Conclusion　117
    References　122
    4　Foreign and Domestic Inventions and Patents　129
    4.1　Foreign Inventions and Patents　129
    4.1.1　Hydrogenation Methods　129
    4.1.2　Esterification Methods　133
    4.2　Domestic Inventions and Patents　134
    4.2.1　A Catalyst for Hydrogenating Dimethyl Terephthalates to Dimethyl Cyclohexane-1,4-Dicarboxylates and the Preparation Thereof(2001)[11]　134
    4.2.2　A Plasticizer Containing Cyclohexane Multi-carboxylate and its Preparation Method(2006)[12]　135
    4.2.3　A Catalyst for Preparing Cyclohexane-1,2-Dicarbolxylates(2008)[13]　136
    4.2.4　A Method for Preparing Cyclohexane-1,2-Dicarboxylates (2008)[14]　137
    4.2.5　A Method for Preparing Environmentally Friendly Di(2-ethylhexyl) Cyclohexane-1,2-Dicarboxylate(DEHCH)(2009)[15]　139
    4.2.6　A Method for Preparing Environmentally Friendly Di(2-ethylhexyl) Cyclohexane-1,2-Dicarboxylate(DEHCH)Plasticizer(2011)[16]　140
    4.2.7　A Method for Preparing Cyclohexane-1,2-Dicarboxylates Using Organic Acid Catalysts(2010)[17]　141
    4.2.8　A Method for Preparing Cyclohexane-1,2-Dicarboxylates Using Ionic Liquid Catalysts(2010)[18]　142
    4.2.9　A Type of Catalysts for Hydrogenating Benzenecarboxylates to Cyclohexanecarboxylates and the Preparation Method Thereof(2012)[19]　143
    4.2.10　A Type of Benzenecarboxylate Hydrogenation Catalyst and the Preparation and Application Thereof(2012)[21]　146
    4.2.11　Catalysts for Hydrogenating Benzenecarboxylate to Cyclohexanecarboxylates and the Preparation and Application Thereof(2012)[20]　147
    4.2.12　A Method for Preparing Diisooctyl Cyclohexane-1,2-Dicarboxylate Plasticizer(2012)[21]　150
    4.2.13　A Method for Preparing the Catalysts for Hydrogenation-Based Cyclohexane-1,2-Dicarboxylates(2012)[22]　151
    4.2.14　A Method for Preparing Diisooctyl Cyclohexane-1,2-Dicarboxylates via Hydrogenation(2012)[23]　153
    4.2.15　A Method for Preparing Cyclohexane-1,2-Dicarboxylates via Hydrogenation(2012)[24]　154
    4.2.16　A Method for Preparing Environmentally Friendly Cyclohexane-1,2-Dicarboxylates(2013)[25]　155
    4.2.17　A Method for Preparing Phthalate Selective Hydrogenation Catalysts(2013)[26]　156
    4.2.18　A Method for Preparing Phthalate Hydrogenation Catalysts(2015)[27]　158
    4.2.19　An Integrated Method for Preparing Cyclohexane-1,2-Dicarboxylates(2015)　159
    4.2.20　A Type of Efficient Plasticizer Hydrogenation Catalysts and their Preparation Method(2013)　161
    4.2.21　A Type of Non-linear Plasticizers and the Preparation and Applications Thereof(2013)　162
    4.2.22　A Type of Apparatus for Preparing Dioctyl Cyclohexane-1,4-Dicarboxylate(2013)　163
    4.2.23　The Esterification Reaction Protocols for DOTP Plasticizer(2015)　165
    4.2.24　A Method for Preparing Cyclohexane-1,2-Dicarboxylates(2015)　166
    4.2.25　A Method for Preparing Environmentally Friendly Plasticizers(2015)　168
    4.2.26　A Method for Preparing Hexahydrophthalic Anhydride(2016)　169
    4.2.27　A Method for Preparing Dioctyl Cyclohexane-1,4-Dicarboxylate(2016)　170
    4.2.28　A Method for Preparing the Catalysts used for Preparing Cyclohexane Dicarboxylates(2016)　172
    4.3　Conclusion　174
    References　180
    5　Catalytic Ring Hydrogenation of Phthalate Plasticizers　183
    5.1　Ring Hydrogenation of Phthalates　183
    5.1.1　Experimental　186
    5.1.2　Effects of Various Factors　188
    5.1.3　Effects of S Content in DOP　193
    5.1.4　Qualitative Analysis of Products　197
    5.1.5　Separation and Purification of Products　199
    5.1.6　Repeatability of Catalytic Hydrogenation　201
    5.1.7　Conclusions　202
    5.2　Multi-phase Catalysis Kinetics of DOP Hydrogenation　204
    5.2.1 Effects of Concentration on DOP Hydrogenation Rate　208
    5.2.2　Arrhenius Equation of Phthalate Hydrogenation Reaction　218
    5.2.3　Conclusions　220
    5.3　Characterizations of Catalysts　220
    5.3.1　XRD　221
    5.3.2　Tem　222
    5.3.3　Texture Analysis of Catalysts　223
    5.3.4　XPS　226
    5.4　Reaction Mechanisms of Catalytic Phthalate Hydrogenation　226
    5.5　Characterizations of PVC Plasticized by Cyclohexane-1,2-Dicarboxylates and Phthalates　227
    5.5.1　Mechanical Properties of PVC/DEHCH and PVC/DOP CompositeMaterials　228
    5.5.2　Thermal Properties of PVC/DEHCH and PVC/DOP CompositeMaterials　233
    5.5.3　Dynamic Mechanical Analysis of PVC/DEHCH and PVC/DOP CompositeMaterials　238
    5.5.4　Rheology of PVC/DOP and PVC/DEHCH CompositeMaterials　240
    5.5.5　Solvent Extraction Resistance of PVC Samples with Different DEHCH and DOP Contents　243
    5.5.6　Evaporation Resistance of PVC Composite Materials with Different DEHCH and DOP Contents　245
    5.5.7　Photonic Properties of PVC Composite Materials with Different DEHCH and DOP Contents　246
    5.5.8　Conclusions　247
    5.6　Third-Party Inspections　247
    5.6.1　Physico-Chemical Property Inspection for Ring-Hydrogenated Products　248
    5.6.2　Toxicity Test of Ring Hydrogenation Product　249
    5.6.3　Ring-Hydrogenated Product Pellets and PVC Articles　252
    References　258
    6　Pilot Demo and Industrialization　261
    6.1　Pilot Demo Studies　261
    6.2　Industrialization Design of 50 k Ton/y Scale Phthalate Hydrogenation　264
    6.2.1　Design Flowchart　264
    6.2.2　Hydrogenation System　265
    6.2.3　Separation and Purification System　266
    6.2.4　Catalyst Recycling System　267
    6.2.5　Exhaust Recycling System　268
    6.3　Industrial Catalyst Production　270
    6.4　Industrial Standards of Cyclohexane-Based Plasticizers　271
    6.4.1　Scope　271
    6.4.2　Normative References　271
    6.4.3　Test Methods　272
    6.4.4　Inspection Rules　275
    6.4.5　Industrial Standard Numbers and Technical Index　276
    6.5　Third-Party Inspections　279
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