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分子光谱
  • 书号:7030108825
    作者:林国强
  • 外文书名:
  • 丛书名:中科院研究生教学丛书
  • 装帧:
    开本:B5
  • 页数:484
    字数:760000
    语种:
  • 出版社:科学出版社
    出版时间:2003-01-14
  • 所属分类:Z89 文摘、索引
  • 定价: ¥45.00元
    售价: ¥36.00元
  • 图书介质:

  • 购买数量: 件  商品库存: 2
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本书为中国科学院研究生教学丛书之一。
本书为化学工作者提供了最新的分子光谱理论与应用信息,内容覆盖了原子光谱、转动光谱、振动光谱及电子光谱,并特别讨论了凝聚相分子光谱。本书从简要说明量子力学原理入手,系统介绍了光的性质、物质的电磁性质及电动力学等知识,结构安排合理,便于读者理解和掌握。
本书可供从事化学,特别是物理化学研究工作的大学高年级本科生、研究生、教师及广大的科研工作者参考。
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目录

  • PREFACE
    1 INTRODUCTION AND REVIEW
    1.1Historical Perspective
    1.2Definitions,Derivations,and Discovery
    1.3Review of Quantum Mechanics
    1.4Approximate Solutions to the Schrodinger Equation
    1.5Statistical Mechanics
    1.6Summary
    1.7Problems
    BIBLIOGRAPHY
    2 THE NATURE OF ELECTROMAGNETIC RADIATION
    2.1Introduction
    2.2The Classical Description of Electromagnetic Radiation
    2.3Propagation of Light in Matter
    2.4Quantum Mechanical Aspects of Light
    2.5Summary
    2.6Problems
    BIBLIOGRAPHY
    3 ELECTRIC AND MAGNETIC PROPERTIES OF MOLECULES AND BULK MATTER
    3.1Introduction
    3.2Electric Properties of Molecules
    3.3Electric Properties of Bulk Matter
    3.4Magnetic Properties of Matter
    3.5Summary
    3.6Problems
    BIBLIOGRAPHY
    4 TIME-DEPENDENT PERTURBATION THEORY OF SPECTROSCOPY
    4.1Introduction:Time Dependence in Quantum Mechanics
    4.2Time-Dependent Perturbation Theory
    4.3Rate Expression for Emission
    4.4Perturbation Theory Calculation of Polarizability
    4.5Quantum Mechanical Expression for Emission Rate
    4.6Time Dependence of the Density Matrix
    4.7Summary
    4.8Problems
    BIBLIOGRAPHY
    5 THE TIME-DEPENDENT APPROACH TO SPECTROSCOPY
    5.1Introduction
    5.2Tim-Correlation Functions and Spectra as Fourier Transform Pairs
    5.3Properties of Time-Correlation Functions and Spectral Lineshapes
    5.4The Fluctuation-Dissipation Theorem
    5.5Rotational Correlation Functions and Pure Rotational Spectra
    5.6Reorientational Spectroscopy of Liquids
    5.7Vibration-Rotation Spectra
    5.8Spectral Moments
    5.9Summary
    5.10Problems
    BIBLIOGRAPHY
    6 EXPERIMENTAL CONSIDERATIONS:ABSORPTION,EMISSION,AND SCATTERING
    6.1Introduction
    6.2Einstein A and B Coefficients for Absorption and Emission
    6.3Absorption and Stimulated Emission
    6.4Absorption and Emission Spectroscopy
    6.5Measurement of Light Scattering:The Raman and Rayleigh Effects
    6.6Spectral Lineshapes
    6.7Summary
    6.8Problems
    BIBLIOGRAPHY
    7 ATOMIC SPECTROSCOPY
    7.1Introduction
    7.2Good Quantum Numbers and Not So Good Quantum Numbers
    7.3Selection Rules for Atomic Absorption and Emission
    7.4The Effect to External Fields
    7.5Atomic Lasers and the Principles of Laser Emission
    7.6Summary
    7.7Problems
    BIBLIOGRAPHY
    8 ROTATIONAL SPECTROSCOPY
    8.1Introduction
    8.2Energy Levels of Free Rigid Rotors
    8.3Angular Momentum Coupling in Non-1∑Electronic States
    8.4Nuclear Statistics and J States of Homonuclear Diatomic
    8.5Rotational Absorption and Emission Spectroscopy
    8.6Rotational Raman Spectroscopy
    8.7Corrections to the Rigid-Rotor Approximation
    8.8Internal Rotation
    8.9Summary
    8.10Problems
    BIBLIOGRAPHY
    9 VIBRATIONAL SPECTROSCOPY OF DIATOMICS
    9.1Introduction
    9.2The Born-Oppenheimer Approximation and Its Consequences
    9.3The Harmonic Oscillator Model
    9.4Selection Rules for Vibrational Transitions
    9.5Beyond the Rigid Rotor-Harmonic Oscillator Approximation
    9.6Summary
    9.7Problems
    BIBLIOGRAPHY
    10 VIBRATIONAL SPECTROSCOPY OF POLYATOMIC MOLECULES
    10.1Introduction
    10.2Normal Modes of Vibration
    10.3Quantum Mechanics of Polyatiomic Vibrations
    10.4Group Theoretical Treatment of Vibrations
    10.5Selection Rules for Infrared and Raman Scattering
    10.6Rotatinoal Structure
    10.7Anharmonicity
    10.8Selection Rules at Work:Benzene
    10.9Solvent Effects on Infrared Spectra
    10.10Summary
    10.11Problems
    BIBLIOGRAPHY
    11 ELECTRONIC SPECTROSCOPY
    11.1Introduction
    11.2Diatomic Molecules:Electronic States and Selection Rules
    11.3Vibuational Structure in Electronic Spectra of Diatomics
    11.4Born-Oppenheimer Breakdown in Diatomic Molecules
    11.5Polyatomic Molecules:Electronic States and Selection Rules
    11.6Transition Metal Complexes
    11.7Emission Spectroscopy of Polyatomic Molecules
    11.8Chromophores
    11.9Solvent Effects in Electronic Spectroscopy
    11.10Summary
    11.11Problems
    BIBLIOGRAPHY
    12 RAMAN AND RESONANCE RAMAN SPECTROSCOPY
    12.1Introduction
    12.2Selection Rules in Raman Scattering
    12.3Polarization in Raman Scattering
    12.4Rotational and Vibrational Dynamics in Raman Scattering
    12.5Analysis of Raman Excitation Profiles
    12.6Time-Dependent Theory of Resonance Raman Spectra
    12.7Raman Scattering as a Third-Order Nonlinear Process
    12.8Summary
    12.9Problems
    BIBLIOGRAPHY
    A.MATH REVIEW
    A.1Vectors and Tensors in Three Dimensions
    A.2Matrices
    A.3Operations with Cartesian and Spherical Tensors
    A.4Spherical harmonics
    A.5Wigner Rotation Functions and Spherical Tensors
    A.6The Clebsch-Gordan Series and 3j Symbols
    BIBLIOGRAPHY
    B.PRINCIPLES OF ELECTROSTATICS
    B.1Units
    B.2Some Applications of Gauss'Law
    B.3Some Mathematical Detalis
    C.GROUP THEORY
    C.1Point Groups and Symmetry Operations
    C.2Information Conveyed by Character Tables
    C.3Direct Products and Reducible Representations
    C.4Character Tables
    BIBLIOGRAPHY
    SUBJECT INDEX
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